Researchers at the SLAC National Accelerator Laboratory in the US have produced the world’s most powerful ultrashort electron beam to date, concentrating petawatt-level peak powers into femtosecond-long pulses at an energy of 10 GeV and a current of around 0.1 MA. According to officials at SLAC’s Facility for Advanced Accelerator Experimental Tests (FACET-II), the new beam could be used to study phenomena in materials science, quantum physics and even astrophysics that were not accessible before.

High-energy electron beams are routinely employed as powerful probes in several scientific fields. To produce them, accelerator facilities like SLAC use strong electric fields to accelerate, focus and compress bunches of electrons. This is not easy, because as electrons are accelerated and compressed, they emit radiation and lose energy, causing the beam’s quality to deteriorate.

An optimally compressed beam

To create their super-compressed ultrashort beam, researchers led by Claudio Emma at FACET-II used a laser to shape the electron bunch’s profile with millimetre-scale precision in the first 10 metres of the accelerator, when the beam’s energy is lowest. They then took this modulated electron beam and boosted its energy by a factor of 100 in a kilometre-long stretch of downstream accelerating cavities. The last step was to compress the beam by a factor of 1000 by using magnets to turn the beam’s millimetre-scale features into a micron-sized long current spike.

One of the biggest challenges, Emma says, was to optimise the laser-based modulation of the beam in tandem with the accelerating cavity and magnetic fields of the magnets to obtain the optimally compressed beam at the end of the accelerator. “This was a large parameter space to work in with lots of knobs to turn and it required careful iteration before an optimum was found,” Emma says.

Measuring the ultra-short electron bunches was also a challenge. “These are typically so intense that if you intercept them with, for example, scintillating screens (a typical technique used in accelerators to diagnose properties of the beam like its spot size or bunch length), the beam fields are so strong they can melt these screens,” Emma explains. “To overcome this, we had to use a series of indirect measurements (plasma ionisation and beam-based radiation) along with simulations to diagnose just how strongly compressed and powerful these beams were.”

Beam delivery

According to Emma, generating extremely compressed electron beams is one of the most important challenges facing accelerator and beam physicists today. “It was interesting for us to tackle this challenge at FACET-II, which is a facility designed specifically to do this kind of research on extreme beam manipulation,” he says.

The team has already delivered the new high-current beams to experimenters who work on probing and optimising the dynamics of plasma-based accelerators. Further down the line, they anticipate much wider applications. “In the future we imagine that we will attract interest from users in multiple fields, be they materials scientists, strong-field quantum physicists or astrophysicists, who want to use the beam as a strong relativistic ‘hammer’ to study and probe a variety of natural interactions with the unique tool that we can provide,” Emma tells Physics World.

The researchers’ next step will be to increase the beam’s current by another order of magnitude. “This additional leap will require the use of a different plasma-based compression technique, rather than the current laser-based approach, which we hope to demonstrate at FACET-II in the near future,” Emma reveals.

The present work is described in Physical Review Letters.

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A team of researchers in Switzerland, Germany and the US has observed clear evidence of quantum mechanical interference behaviour in collisions between a methane molecule and a gold surface. As well as extending the boundaries of quantum effects further into the classical world, the team say the work has implications for surface chemistry, which is important for many industrial processes.

The effects of interference in light are generally easy to observe. Whenever a beam of light passes through closely-spaced slits or bounces off an etched grating, an alternating pattern of bright and dark intensity modulations appears, corresponding to locations of constructive and destructive interference, respectively. This was the outcome of Thomas Young’s original double-slit experiment, which was carried out in the 1800s and showed that light behaves like a wave.

For molecules and other massive objects, observing interference is trickier. Though quantum mechanics decrees that these also interfere when they scatter off surfaces, and a 1920s version of Young’s double-slit experiment showed that this was true for electrons, the larger the objects are, the more difficult it is to observe interference effects. Indeed, the disappearance of such effects is a sign that the object’s wavefunction has “decohered” – that is, the object has stopped behaving like a wave and started obeying the laws of classical physics.

Similar to the double-slit experiment

In the new work, researchers led by Rainer Beck of the EPFL developed a way to observe interference in complex polyatomic molecules. They did this by using an infrared laser to push methane (CH₄) molecules into specific rovibrational states before scattering the molecules off an atomically smooth and chemically inert Au(111) surface. They then detected the molecules’ final states using a second laser and an instrument called a bolometer that measures the tiny temperature change as molecules absorb the laser’s energy.

Using this technique, Beck and colleagues identified a pattern in the quantum states of the methane molecules after they collided with the surface. When two states had different symmetries, the quantum mechanical amplitudes for the different pathways taken during the transition between them cancelled out. In states with the same symmetry, however, the pathways reinforced each other, leading to an intense, clearly visible signal.

The researchers say that this effect is similar to the destructive and constructive interference of the double-slit experiment, but not quite the same. The difference is that interference in the double-slit experiment stems from diffraction, whereas the phenomenon Beck and colleagues observed relates to the rotational and vibrational states of the methane molecules.

A rule to explain the patterns

The researchers had seen hints of such behaviour in experiments a few years ago, when they scattered methane from a nickel surface. “We saw that some rotational quantum states were somewhat weakly populated by the collisions while other states that were superficially very similar (that is, with the same energy and same angular momentum) were more strongly populated,” explains Christopher Reilly, a postdoctoral researcher at EPFL and the lead author of a paper in Science on the work. “When we moved on to collisions with a gold surface, we discovered that these population imbalances were now very pronounced.”

This discovery spurred them to find an explanation. “We concluded that we might be observing a conservation of the reflection parity of the methane molecule’s wavefunction,” Reilly says. “We then set out to test it for molecules prepared in vibrationally excited states and our results confirmed our hypothesis spectacularly.”

Because the team’s technique for detecting quantum states relies on spectroscopy, Reilly says the “intimidating complexity” of the spectrum of quantum states in a medium-sized molecule like methane was a challenge. “While our narrow-bandwidth lasers allowed us to probe the population in individual quantum states, we still needed to know exactly which wavelength we need to tune the laser wavelength to in order to address a given state,” he explains.

This, in turn, meant knowing the molecule’s energy levels very precisely, as they were trying to compare populations of states with only marginally different energies. “It is only just in the last couple years that modelling of methane’s spectrum has become accurate enough to permit a reliable assignment of the quantum states involved in a given infrared transition,” Reilly says, adding that the HITEMP project of the HITRAN spectroscopic database was a big help.

Rethinking molecule-surface dynamics

According to Reilly, the team’s results show that classical models cannot fully capture molecule-surface dynamics. “This has implications for our general understanding of chemistry at surfaces, which is where in fact the majority of chemistry relevant to industry (think catalysts) and technology (think semiconductors) occurs,” he says. “The first step of any surface reaction is the adsorption of the reactants onto the surface and this step often requires the overcoming of some energetic barrier. Whether an incoming molecule will adsorb depends not only on the molecule’s total energy but on whether this energy can be effectively channelled into overcoming the barrier.

“Our scattering experiments directly probe these dynamics and show that, to really understand the different fundamental steps of surface chemistry, quantum mechanics is needed,” he tells Physics World.

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Water molecules on the surface of an electrode flip just before they give up electrons to form oxygen – a feat of nanoscale gymnastics that explains why the reaction takes more energy than it theoretically should. After observing this flipping in individual water molecules for the first time, scientists at Northwestern University in the US say that the next step is to find ways of controlling it. Doing so could improve the efficiency of the reaction, making it easier to produce both oxygen and hydrogen fuel from water.

The water splitting process takes place in an electrochemical cell containing water and a metallic electrode. When a voltage is applied to the electrode, the water splits into oxygen and hydrogen via two separate half-reactions.

The problem is that the half-reaction that produces oxygen, known as the oxygen evolution reaction (OER), is difficult and inefficient and takes more energy than predicted by theory. “It should require 1.23 V,” says Franz Geiger, the Northwestern physical chemist who led the new study, “but in reality, it requires more like 1.5 or 1.8 V.” This extra energy cost is one of the reasons why water splitting has not been implemented on a large scale, he explains.

Determining how water molecules arrange themselves

In the new work, Geiger and colleagues wanted to test whether the orientation of the water’s oxygen atoms affects the kinetics of the OER. To do this, they directed an 80-femtosecond pulse of infrared (1034 nm) laser light onto the surface of the electrode, which was in this case made of nickel. They then measured the intensity of the reflected light at half the incident wavelength.

This method, which is known as second harmonic and vibrational sum-frequency generation spectroscopy, revealed that the water molecules’ alignment on the surface of the electrode depended on the applied voltage. By analysing the amplitude and phase of the signal photons as this voltage was cycled, the researchers were able to pin down how the water molecules arranged themselves.

They found that before the voltage was applied, the water molecules were randomly oriented. At a specific applied voltage, however, they began to reorient. “We also detected water dipole flipping just before cleavage and electron transfer,” Geiger adds. “This allowed us to distinguish flipping from subsequent reaction steps.”

An unexplored idea

The researchers’ explanation for this flipping is that at high pH levels, the surface of the electrode is negatively charged due to the presence of nickel hydroxide groups that have lost their protons. The water molecules therefore align with their most positively charged ends facing the electrode. However, this means that the ends containing the electrons needed for the OER (which reside in the oxygen atoms) are pointing away from the electrode. “We hypothesized that water molecules must flip to align their oxygen atoms with electrochemically active nickel oxo species at high applied potential,” Geiger says.

This idea had not been explored until now, he says, because water absorbs strongly in the infrared range, making it appear opaque at the relevant frequencies. The electrodes typically employed are also too thick for infrared light to pass through. “We overcame these challenges by making the electrode thin enough for near-infrared transmission and by using wavelengths where water’s absorbance is low (the so-called ‘water window’),” he says.

Other challenges for the team included designing a spectrometer that could measure the second harmonic generation amplitude and phase and developing an optical model to extract the number of net-aligned water molecules and their flipping energy. “The full process – from concept to publication – took three years,” Geiger tells Physics World.

The team’s findings, which are detailed in Science Advances, suggest that controlling the orientation of water at the interface with the electrode could improve OER catalyst performance. For example, surfaces engineered to pre-align water molecules might lower the kinetic barriers to water splitting. “The results could also refine electrochemical models by incorporating structural water energetics,” Geiger says. “And beyond the OER, water alignment may also influence other reactions such as the hydrogen evolution reaction and CO₂ reduction to liquid fuels, potentially impacting multiple energy-related technologies.”

The researchers are now exploring alternative electrode materials, including NiFe and multi-element catalysts. Some of the latter can outperform iridium, which has traditionally been the best-performing electrocatalyst, but is very rare (it comes from meteorites) and therefore expensive. “We have also shown in a related publication (in press) that water flipping occurs on an earth-abundant semiconductor, suggesting broader applicability beyond metals,” Geiger reveals.

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If a water droplet flowing over a surface gets stuck, and then unsticks itself, it generates an electric charge. The discoverers of this so-called depinning phenomenon are researchers at RMIT University and the University of Melbourne, both in Australia, and they say that boosting it could make energy-harvesting devices more efficient.

The newly observed charging mechanism is conceptually similar to slide electrification, which occurs when a liquid leaves a surface – that is, when the surface goes from wet to dry. However, the idea that the opposite process can also generate a charge is new, says Peter Sherrell, who co-led the study. “We have found that going from dry to wet matters as well and may even be (in some cases) more important,” says Sherrell, an interdisciplinary research fellow at RMIT. “Our results show how something as simple as water moving on a surface still shows basic phenomena that have not been understood yet.”

Co-team leader Joe Berry, a fluid dynamics expert at Melbourne, notes that the charging mechanism only occurs when the water droplet gets temporarily stuck on the surface. “This suggests that we could design surfaces with specific structure and/or chemistry to control this charging,” he says. “We could reduce this charge for applications where it is a problem – for example in fuel handling – or, conversely, enhance it for applications where it is a benefit. These include increasing the speed of chemical reactions on catalyst surfaces to make next-generation batteries more efficient.”

More than 500 experiments

To observe depinning, the researchers built an experimental apparatus that enabled them to control the sticking and slipping motion of a water droplet on a Teflon surface while measuring the corresponding change in electrical charge. They also controlled the size of the droplet, making it big enough to wet the surface all at once, or smaller to de-wet it. This allowed them to distinguish between multiple mechanisms at play as they sequentially wetted and dried the same region of the surface.

Their study, which is published in Physical Review Letters, is based on more than 500 wetting and de-wetting experiments performed by PhD student Shuaijia Chen, Sherrell says. These experiments showed that the largest change in charge – from 0 to 4.1 nanocoulombs (nC) – occurred the first time the water contacted the surface. The amount of charge then oscillated between about 3.2 and 4.1 nC as the system alternated between wet and dry phases. “Importantly, this charge does not disappear,” Sherrell says. “It is likely generated at the interface and probably retained in the droplet as it moves over the surface.”

The motivation for the experiment came when Berry asked Sherrell a deceptively simple question: was it possible to harvest electricity from raindrops? To find out, they decided to supervise a semester-long research project for a master’s student in the chemical engineering degree programme at Melbourne. “The project grew from there, first with two more research project students [before] Chen then took over to build the final experimental platform and take the measurements,” Berry recalls.

The main challenge, he adds, was that they did not initially understand the phenomenon they were measuring. “Another obstacle was to design the exact protocol required to repeatedly produce the charging effect we observed,” he says.

Potential applications

Understanding how and why electric charge is generated as liquids flow during over surfaces is important, Berry says, especially with new, flammable types of renewable fuels such as hydrogen and ammonia seen as part of the transition to net zero. “At present, with existing fuels, charge build-up is reduced by restricting flow using additives or other measures, which may not be effective in newer fuels,” he explains. “This knowledge may help us to engineer coatings that could mitigate charge in new fuels.”

The RMIT/Melbourne researchers now plan to investigate the stick-slip phenomenon with other types of liquids and surfaces and are keen to partner with industries to target applications that can make a real-world impact. “At this stage, we have simply reported that this phenomenon occurs,” Sherrell says. “We now want to show that we can control when and where these charging events happen – either to maximize them or eliminate them. We are still a long way off from using our discovery for chemical and energy applications – but it’s a big step in the right direction.”

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An international team led by chemists at the University of British Columbia (UBC), Canada, has reported strong experimental evidence for a superfluid phase in molecular hydrogen at 0.4 K. This phase, theoretically predicted in 1972, had only been observed in helium and ultracold atomic gases until now, and never in molecules. The work could give scientists a better understanding of quantum phase transitions and collective phenomena. More speculatively, it could advance the field of hydrogen storage and transportation.

Superfluidity is a quantum mechanical effect that occurs at temperatures near absolute zero. As the temperatures of certain fluids approach this value, they undergo a transition to a zero-viscosity state and begin to flow without resistance – behaviour that is fundamentally different to that of ordinary liquids.

Previously, superfluidity had been observed in helium (³He and ⁴He) and in clusters of ultracold atoms known as Bose-Einstein condensates. In principle, molecular hydrogen (H₂), which is the simplest and lightest of all molecules, should also become superfluid at ultracold temperatures. Like ⁴He, H₂ is a boson, so it is theoretically capable of condensing into a superfluid phase. The problem is that it is only predicted to enter this superfluid state at a temperature between 1 and 2 K, which is lower than its freezing point of 13.8 K.

A new twist on a spinning experiment

To keep their molecular hydrogen liquid below its freezing point, team leader Takamasa Momose and colleagues at UBC confined small clusters of hydrogen molecules inside helium nanodroplets at 0.4 K. They then embedded a methane molecule in the hydrogen cluster and observed its rotation with laser spectroscopy.

Momose describes this set-up as a miniature version of an experiment performed by the Georgian physicist Elephter Andronikashvili in 1946, which showed that disks inside superfluid helium could rotate without resistance. They chose methane as their “disk”, Momose explains, because it rotates quickly and interacts only very weakly with H₂, meaning it does not disturb the behaviour of the medium in which it spins.

Onset of superfluidity

In clusters containing less than six hydrogen molecules, they observed some evidence of friction affecting the methane’s rotation. As the clusters grew to 10 molecules, this friction began to disappear and the spinning methane molecule rotated faster, without resistance. This implies that most of the hydrogen molecules around it are behaving as a single quantum entity, which is a signature of superfluidity. “For clusters larger than N = 10, the hydrogen acted like a perfect superfluid, confirming that it flows with zero resistance,” Momose tells Physics World.

The researchers, who have been working on this project for nearly 20 years, say they took it on because detecting superfluidity in H₂ is “one of the most intriguing unanswered questions in physics – debated for 50 years”. As well as working out how to keep hydrogen in a liquid state at extremely low temperatures, they also had to find a way to detect the onset of superfluidity with high enough precision. “By using methane as a probe, we were finally able to measure how hydrogen affects its motion,” Momose says.

A deeper understanding

The team say the discovery opens new avenues for exploring quantum fluids beyond helium. This could lead scientists to a deeper understanding of quantum phase transitions and collective quantum phenomena, Momose adds.

The researchers now plan to study larger hydrogen clusters (ranging from N = 20 to over a million) to understand how superfluidity evolves with size and whether the clusters eventually freeze or remain fluid. “This will help us explore the boundary between quantum and classical matter,” Momose explains.

They also want to test how superfluid hydrogen responds to external stimuli such as electric and magnetic fields. Such experiments could reveal even more fascinating quantum behaviours and deepen our understanding of molecular superfluidity, Momose says. They could also have practical applications, he adds.

“From a practical standpoint, hydrogen is a crucial element in clean energy technologies, and understanding its quantum properties could inspire new approaches for hydrogen storage and transportation,” he says. “The results from these [experiments] may also provide critical insights into achieving superfluidity in bulk liquid hydrogen – an essential step toward harnessing frictionless flow for more efficient energy transport systems.”

The researchers report their work in Science Advances.

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Scientists in the US have developed a new type of photovoltaic battery that runs on the energy given off by nuclear waste. The battery uses a scintillator crystal to transform the intense gamma rays from radioisotopes into electricity and can produce more than a microwatt of power. According to its developers at Ohio State University and the University of Toledo, it could be used to power microelectronic devices such as microchips.

The idea of a nuclear waste battery is not new. Indeed, Raymond Cao, the Ohio State nuclear engineer who led the new research effort, points out that the first experiments in this field date back to the early 1950s. These studies, he explains, used a 50 milli-Curie ⁹⁰Sr-⁹⁰Y source to produce electricity via the electron-voltaic effect in p-n junction devices.

However, the maximum power output of these devices was just 0.8 μW, and their power conversion efficiency (PCE) was an abysmal 0.4 %. Since then, the PCE of nuclear voltaic batteries has remained low, typically in the 1–3% range, and even the most promising devices have produced, at best, a few hundred nanowatts of power.

Exploiting the nuclear photovoltaic effect

Cao is confident that his team’s work will change this. “Our yet-to-be-optimized battery has already produced 1.5 μW,” he says, “and there is much room for improvement.”

To achieve this benchmark, Cao and colleagues focused on a different physical process called the nuclear photovoltaic effect. This effect captures the energy from highly-penetrating gamma rays indirectly, by coupling a photovoltaic solar cell to a scintillator crystal that emits visible light when it absorbs radiation. This radiation can come from several possible sources, including nuclear power plants, storage facilities for spent nuclear fuel, space- and submarine-based nuclear reactors or, really, anyplace that happens to have large amounts of gamma ray-producing radioisotopes on hand.

The scintillator crystal Cao and colleagues used is gadolinium aluminium garnet (GAGG), and they attached it to a solar cell made from polycrystalline CdTe. The resulting device measures around 2 x 2 x 1 cm, and they tested it using intense gamma rays emitted by two different radioactive sources, ¹³⁷Cs and ⁶⁰Co, that produced 1.5 kRad/h and 10 kRad/h, respectively. ¹³⁷Cs is the most common fission product found in spent nuclear fuel, while ⁶⁰Co is an activation product.

Enough power for a microsensor

The Ohio-Toledo team found that the maximum power output of their battery was around 288 nW with the ¹³⁷Cs source. Using the ⁶⁰Co irradiator boosted this to 1.5 μW. “The greater the radiation intensity, the more light is produced, resulting in increased electricity generation,” Cao explains.

The higher figure is already enough to power a microsensor, he says, and he and his colleagues aim to scale the system up to milliwatts in future efforts. However, they acknowledge that doing so presents several challenges. Scaling up the technology will be expensive, and gamma radiation gradually damages both the scintillator and the solar cell. To overcome the latter problem, Cao says they will need to replace the materials in their battery with new ones. “We are interested in finding alternative scintillator and solar cell materials that are more radiation-hard,” he tells Physics World.

The researchers are optimistic, though, arguing that optimized nuclear photovoltaic batteries could be a viable option for harvesting ambient radiation that would otherwise be wasted. They report their work in Optical Materials X.

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A new technique could reduce the risk of blood clots associated with medical implants, making them safer for patients. The technique, which was developed by researchers at the University of Sydney, Australia, involves coating the implants with highly hydrophilic molecules known as zwitterions, thereby inhibiting the build-up of clot-triggering proteins.

Proteins in blood can stick to the surfaces of medical implants such as heart valves and vascular stents. When this happens, it produces a cascade effect in which multiple mechanisms lead to the formation of extensive clots and fibrous networks. These clots and networks can impair the function of implanted medical devices so much that invasive surgery may be required to remove or replace the implant.

To prevent this from happening, the surfaces of implants are often treated with polymeric coatings that resist biofouling. Hydrophilic polymeric coatings such as polyethylene glycol are especially useful, as their water-loving nature allows a thin layer of water to form between them and the surface of the implants, held in place via hydrogen and/or electrostatic bonds. This water layer forms a barrier that prevents proteins from sticking, or adsorbing, to the implant.

An extra layer of zwitterions

Recently, researchers discovered that polymers coated with an extra layer of small molecules called zwitterions provided even more protection against protein adsorption. “Zwitter” means “hybrid” in German; hence, zwitterions are molecules that carry both positive and negative charge, making them neutrally charged overall. These molecules are also very hydrophilic and easily form tight bonds with water molecules. The resulting layer of water has a structure that is similar to that of bulk water, which is energetically stable.

A further attraction of zwitterionic coatings for medical implants is that zwitterions are naturally present in our bodies. In fact, they make up the hydrophilic phospholipid heads of mammalian cell membranes, which play a vital role in regulating interactions between biological cells and the extracellular environment.

Plasma functionalization

In the new work, researchers led by Sina Naficy grafted nanometre-thick zwitterionic coatings onto the surfaces of implant materials using a technique called plasma functionalization. They found that the resulting structures reduce the amount of fibrinogen proteins that adsorb onto the implants by roughly nine-fold and decrease blood clot formation (thrombosis) by almost 75%.

Naficy and colleagues achieved their results by optimizing the density, coverage and thickness of the coating. This was critical for realizing the full potential of these materials, they say, because a coating that is not fully optimized would not reduce clotting.

Naficy tells Physics World that the team’s main goal is to enhance the surface properties of medical devices. “These devices when implanted are in contact with blood and can readily cause thrombosis or infection if the surface initiates certain biological cascade reactions,” he explains. “Most such reactions begin when specific proteins adsorb on the surface and activate the next stage of cascade. Optimizing surface properties with the aid of zwitterions can control / inhibit protein adsorption, hence reducing the severity of adverse body reactions.”

The researchers say they will now be evaluating the long-term stability of the zwitterion-polymer coatings and trying to scale up their grafting process. They report their work in Communications Materials and Cell Biomaterials.

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A new artificial intelligence/machine learning method rapidly and accurately characterizes binary neutron star mergers based on the gravitational wave signature they produce. Though the method has not yet been tested on new mergers happening “live”, it could enable astronomers to make quicker estimates of properties such as the location of mergers and the masses of the neutron stars. This information, in turn, could make it possible for telescopes to target and observe the electromagnetic signals that accompany such mergers.

When massive objects such as black holes and neutron stars collide and merge, they emit ripples in spacetime known as gravitational waves (GWs). In 2015 scientists on Earth began observing these ripples using kilometre-scale interferometers that measure the minuscule expansion and contraction of space–time that occurs when a gravitational wave passes through our planet. These interferometers are located in the US, Italy and Japan and are known collectively as the LVK observatories after their initials: the Laser Interferometer GW Observatory (LIGO), the Virgo GW Interferometer (Virgo) and the Kamioka GW Detector (KAGRA).

When two neutron stars in a binary pair merge, they emit electromagnetic waves as well as GWs. While both types of wave travel at the speed of light, certain poorly understood processes that occur within and around the merging pair cause the electromagnetic signal to be slightly delayed. This means that the LVK observatories can detect the GW signal coming from a binary neutron star (BNS) merger seconds, or even minutes, before its electromagnetic counterpart arrives. Being able to identify GWs quickly and accurately therefore increases the chances of detecting other signals from the same event.

This is no easy task, however. GW signals are long and complex, and the main technique currently used to interpret them, Bayesian inference, is slow. While faster alternatives exist, they often make algorithmic approximations that negatively affect their accuracy.

Trained with millions of GW simulations

Physicists led by Maximilian Dax of the Max Planck Institute for Intelligent Systems in Tübingen, Germany have now developed a machine learning (ML) framework that accurately characterizes and localizes BNS mergers within a second of a GW being detected, without resorting to such approximations. To do this, they trained a deep neural network model with millions of GW simulations.

Once trained, the neural network can take fresh GW data as input and predict corresponding properties of the merging BNSs – for example, their masses, locations and spins – based on its training dataset. Crucially, this neural network output includes a sky map. This map, Dax explains, provides a fast and accurate estimate for where the BNS is located.

The new work built on the group’s previous studies, which used ML systems to analyse GWs from binary black hole (BBH) mergers. “Fast inference is more important for BNS mergers, however,” Dax says, “to allow for quick searches for the aforementioned electromagnetic counterparts, which are not emitted by BBH mergers.”

The researchers, who report their work in Nature, hope their method will help astronomers to observe electromagnetic counterparts for BNS mergers more often and detect them earlier – that is, closer to when the merger occurs. Being able to do this could reveal important information on the underlying processes that occur during these events. “It could also serve as a blueprint for dealing with the increased GW signal duration that we will encounter in the next generation of GW detectors,” Dax says. “This could help address a critical challenge in future GW data analysis.”

So far, the team has focused on data from current GW detectors (LIGO and Virgo) and has only briefly explored next-generation ones. They now plan to apply their method to these new GW detectors in more depth.

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Researchers at the EMBL in Germany have dramatically reduced the time required to create images using Brillouin microscopy, making it possible to study the viscoelastic properties of biological samples far more quickly and with less damage than ever before. Their new technique can image samples with a field of view of roughly 10 000 pixels at a speed of 0.1 Hz – a 1000-fold improvement in speed and throughput compared to standard confocal techniques.

Mechanical properties such as the elasticity and viscosity of biological cells are closely tied to their function. These properties also play critical roles in processes such as embryo and tissue development and can even dictate how diseases such as cancer evolve. Measuring these properties is therefore important, but it is not easy since most existing techniques to do so are invasive and thus inherently disruptive to the systems being imaged.

Non-destructive, label- and contact-free

In recent years, Brillouin microscopy has emerged as a non-destructive, label- and contact-free optical spectroscopy method for probing the viscoelastic properties of biological samples with high resolution in three dimensions. It relies on Brillouin scattering, which occurs when light interacts with the phonons (or collective vibrational modes) that are present in all matter. This interaction produces two additional peaks, known as Stokes and anti-Stokes Brillouin peaks, in the spectrum of the scattered light. The position of these peaks (the Brillouin shift) and their linewidth (the Brillouin width) are related to the elastic and viscous properties, respectively, of the sample.

The downside is that standard Brillouin microscopy approaches analyse just one point in a sample at a time. Because the scattering signal from a single point is weak, imaging speeds are slow, yielding long light exposure times that can damage photosensitive components within biological cells.

“Light sheet” Brillouin imaging

To overcome this problem, EMBL researchers led by Robert Prevedel began exploring ways to speed up the rate at which Brillouin microscopy can acquire two- and three-dimensional images. In the early days of their project, they were only able to visualize one pixel at a time. With typical measurement times of tens to hundreds of milliseconds for a single data point, it therefore took several minutes, or even hours, to obtain two-dimensional images of 50–250 square pixels.

In 2022, however, they succeeded in expanding the field of view to include an entire spatial line — that is, acquiring image data from more than 100 points in parallel. In their latest work, which they describe in Nature Photonics, they extended the technique further to allow them to view roughly 10 000 pixels in parallel over the full plane of a sample. They then used the  new approach to study mechanical changes in live zebrafish larvae.

“This advance enables much faster Brillouin imaging, and in terms of microscopy, allows us to perform ‘light sheet’ Brillouin imaging,” says Prevedel. “In short, we are able to ‘under-sample’ the spectral output, which leads to around 1000 fewer individual measurements than normally needed.”

Towards a more widespread use of Brillouin microscopy

Prevedel and colleagues hope their result will lead to more widespread use of Brillouin microscopy, particularly for photosensitive biological samples. “We wanted to speed-up Brillouin imaging to make it a much more useful technique in the life sciences, yet keep overall light dosages low. We succeeded in both aspects,” he tells Physics World.

Looking ahead, the researchers plan to further optimize the design of their approach and merge it with microscopes that enable more robust and straightforward imaging. “We then want to start applying it to various real-world biological structures and so help shed more light on the role mechanical properties play in biological processes,” Prevedel says.

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New data from the NOvA experiment at Fermilab in the US contain no evidence for so-called “sterile” neutrinos, in line with results from most – though not all – other neutrino detectors to date. As well as being consistent with previous experiments, the finding aligns with standard theoretical models of neutrino oscillation, in which three active types, or flavours, of neutrino convert into each other. The result also sets more stringent limits on how much an additional sterile type of neutrino could affect the others.

“The global picture on sterile neutrinos is still very murky, with a number of experiments reporting anomalous results that could be attributed to sterile neutrinos on one hand and a number of null results on the other,” says NOvA team member Adam Lister of the University of Wisconsin, Madison, US. “Generally, these anomalous results imply we should see large amounts of sterile-driven neutrino disappearance at NOvA, but this is not consistent with our observations.”

Neutrinos were first proposed in 1930 by Wolfgang Pauli as a way to account for missing energy and spin in the beta decay of nuclei. They were observed in the laboratory in 1956, and we now know that they come in (at least) three flavours: electron, muon and tau. We also know that these three flavours oscillate, changing from one to another as they travel through space, and that this oscillation means they are not massless (as was initially thought).

Significant discrepancies

Over the past few decades, physicists have used underground detectors to probe neutrino oscillation more deeply. A few of these detectors, including the LSND at Los Alamos National Laboratory, BEST in Russia, and Fermilab’s own MiniBooNE, have observed significant discrepancies between the number of neutrinos they detect and the number that mainstream theories predict.

One possible explanation for this excess, which appears in some extensions of the Standard Model of particle physics, is the existence of a fourth flavour of neutrino. Neutrinos of this “sterile” type do not interact with the other flavours via the weak nuclear force. Instead, they interact only via gravity.

Detecting sterile neutrinos would fundamentally change our understanding of particle physics. Indeed, some physicists think sterile neutrinos could be a candidate for dark matter – the mysterious substance that is thought to make up around 85% of the matter in the universe but has so far only made itself known through the gravitational force it exerts.

Near and far detectors

The NOvA experiment uses two liquid scintillator detectors to monitor a stream of neutrinos created by firing protons at a carbon target. The near detector is located at Fermilab, approximately 1 km from the target, while the far detector is 810 km away in northern Minnesota. In the new study, the team measured how many muon-type neutrinos survive the journey through the Earth’s crust from the near detector to the far one. The idea is that if fewer neutrinos survive than the conventional three-flavour oscillations picture predicts, some of them could have oscillated into sterile neutrinos.

The experimenters studied two different interactions between neutrinos and normal matter, says team member V Hewes of the University of Cincinnati, US. “We looked for both charged current muon neutrino and neutral current interactions, as a sterile neutrino would manifest differently in each,” Hewes explains. “We then compared our data across those samples in both detectors to simulations of neutrino oscillation models with and without the presence of a sterile neutrino.”

No excess of neutrinos seen

Writing in Physical Review Letters, the researchers state that they found no evidence of neutrinos oscillating into sterile neutrinos. What is more, introducing a fourth, sterile neutrino did not provide better agreement with the data than sticking with the standard model of three active neutrinos.

This result is in line with several previous experiments that looked for sterile neutrinos, including those performed at T2K, Daya Bay, RENO and MINOS+. However, Lister says it places much stricter constraints on active-sterile neutrino mixing than these earlier results. “We are really tightening the net on where sterile neutrinos could live, if they exist,” he tells Physics World.

The NOvA team now hopes to tighten the net further by reducing systematic uncertainties. “To that end, we are developing new data samples that will help us better understand the rate at which neutrinos interact with our detector and the composition of our beam,” says team member Adam Aurisano, also at the University of Cincinnati. “This will help us better distinguish between the potential imprint of sterile neutrinos and more mundane causes of differences between data and prediction.”

NOvA co-spokesperson Patricia Vahle, a physicist at the College of William & Mary in Virginia, US, sums up the results. “Neutrinos are full of surprises, so it is important to check when anomalies show up,” she says. “So far, we don’t see any signs of sterile neutrinos, but we still have some tricks up our sleeve to extend our reach.”

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Physicists in Germany have found an alternative explanation for an anomaly that had previously been interpreted as potential evidence for a mysterious “dark force”. Originally spotted in ytterbium atoms, the anomaly turns out to have a more mundane cause. However, the investigation, which involved high-precision measurements of shifts in ytterbium’s energy levels and the mass ratios of its isotopes, could help us better understand the structure of heavy atomic nuclei and the physics of neutron stars.

Isotopes are forms of an element that have the same number of protons and electrons, but different numbers of neutrons. These different numbers of neutrons produce shifts in the atom’s electronic energy levels. Measuring these so-called isotope shifts is therefore a way of probing the interactions between electrons and neutrons.

In 2020, a team of physicists at the Massachusetts Institute of Technology (MIT) in the US observed an unexpected deviation in the isotope shift of ytterbium. One possible explanation for this deviation was the existence of a new “dark force” that would interact with both ordinary, visible matter and dark matter via hypothetical new force-carrying particles (bosons).

Although dark matter is thought to make up about 85 percent of the universe’s total matter, and its presence can be inferred from the way light bends as it travels towards us from distant galaxies, it has never been detected directly. Evidence for a new, fifth force (in addition to the known strong, weak, electromagnetic and gravitational forces) that acts between ordinary and dark matter would therefore be very exciting.

A team led by Tanja Mehlstäubler from the Physikalisch-Technische Bundesanstalt (PTB) in Braunschweig and Klaus Blaum from the Max Planck Institute for Nuclear Physics (MPIK) in Heidelberg has now confirmed that the anomaly is real. However, the PTB-MPIK researchers say it does not stem from a dark force. Instead, it arises from the way the nuclear structure of ytterbium isotopes deforms as more neutrons are added.

Measuring ytterbium isotope shifts and atomic masses

Mehlstäubler, Blaum and colleagues came to this conclusion after measuring shifts in the atomic energy levels of five different ytterbium isotopes: ^{168,170,172,174,176}Yb. They did this by trapping ions of these isotopes in an ion trap at the PTB and then using an ultrastable laser to drive certain electronic transitions. This allowed them to pin down the frequencies of specific transitions (²S_1/2→²D_5/2 and ²S_1/2→²F_7/2) with a precision of 4 ×10⁻⁹, the highest to date.

They also measured the atomic masses of the ytterbium isotopes by trapping individual highly-charged Yb⁴²⁺ ytterbium ions in the cryogenic PENTATRAP Penning trap mass spectrometer at the MPIK. In the strong magnetic field of this trap, team member and study lead author Menno Door explains, the ions are bound to follow a circular orbit. “We measure the rotational frequency of this orbit by amplifying the miniscule inducted current in surrounding electrodes,” he says. “The measured frequencies allowed us to very precisely determine the related mass ratios of the various isotopes with a precision of 4 ×10⁻¹².”

From these data, the researchers were able to extract new parameters that describe how the ytterbium nucleus deforms. To back up their findings, a group at TU Darmstadt led by Achim Schwenk simulated the ytterbium nuclei on large supercomputers, calculating their structure from first principles based on our current understanding of the strong and electromagnetic interactions. “These calculations confirmed that the leading signal we measured was due to the evolving nuclear structure of ytterbium isotopes, not a new fifth force,” says team member Matthias Heinz.

“Our work complements a growing body of research that aims to place constraints on a possible new interaction between electrons and neutrons,” team member Chih-Han Yeh tells Physics World. “In our work, the unprecedented precision of our experiments refined existing constraints.”

The researchers say they would now like to measure other isotopes of ytterbium, including rare isotopes with high or low neutron numbers. “Doing this would allow us to control for uncertain ‘higher-order’ nuclear structure effects and further improve the constraints on possible new physics,” says team member Fiona Kirk.

Door adds that isotope chains of other elements such as calcium, tin and strontium would also be worth investigating. “These studies would allow to further test our understanding of nuclear structure and neutron-rich matter, and with this understanding allow us to probe for possible new physics again,” he says.

The work is detailed in Physical Review Letters.

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Orthopaedic implants that bear loads while bones heal, then disappear once they’re no longer needed, could become a reality thanks to a new technique for enhancing the mechanical properties of zinc alloys. Developed by researchers at Monash University in Australia, the technique involves controlling the orientation and size of microscopic grains in these strong yet biodegradable materials.

Implants such as plates and screws provide temporary support for fractured bones until they knit together again. Today, these implants are mainly made from sturdy materials such as stainless steel or titanium that remain in the body permanently. Such materials can, however, cause discomfort and bone loss, and subsequent injuries to the same area risk additional damage if the permanent implants warp or twist.

To address these problems, scientists have developed biodegradable alternatives that dissolve once the bone has healed. These alternatives include screws made from magnesium-based materials such as MgYREZr (trade name MAGNEZIX), MgYZnMn (NOVAMag) and MgCaZn (RESOMET). However, these materials have compressive yield strengths of just 50 to 260 MPa, which is too low to support bones that need to bear a patient’s weight. They also produce hydrogen gas as they degrade, possibly affecting how biological tissues regenerate.

Zinc alloys do not suffer from the hydrogen gas problem. They are biocompatible, dissolving slowly and safely in the body. There is even evidence that Zn²⁺ ions can help the body heal by stimulating bone formation. But again, their mechanical strength is low: at less than 30 MPa, they are even worse than magnesium in this respect.

Making zinc alloys strong enough for load-bearing orthopaedic implants is not easy. Mechanical strategies such as hot-extruding binary alloys have not helped much. And methods that focus on reducing the materials’ grain size (to hamper effects like dislocation slip) have run up against a discouraging problem: at body temperature (37 °C), ultrafine-grained Zn alloys become mechanically weaker as their so-called “creep resistance” decreases.

Grain size goes bigger

In the new work, a team led by materials scientist and engineer Jian-Feng Nei tried a different approach. By increasing grain size in Zn alloys rather than decreasing it, the Monash team was able to balance the alloys’ strength and creep resistance – something they say could offer a route to stronger zinc alloys for biodegradable implants.

In compression tests of extruded Zn–0.2 wt% Mg alloy samples with grain sizes of 11 μm, 29 μm and 47 μm, the team measured stress-strain curves that show a markedly higher yield strength for coarse-grained samples than for fine-grained ones. What is more, the compressive yield strengths of these coarser-grained zinc alloys are notably higher than those of MAGNEZIX, NOVAMag and RESOMET biodegradable magnesium alloys. At the upper end, they even rival those of high-strength medical-grade stainless steels.

The researchers attribute this increased compressive yield to a phenomenon called the inverse Hall–Petch effect. This effect comes about because larger grains favour metallurgical effects such as intra-granular pyramidal slip as well as a variation of a well-known metal phenomenon called twinning, in which a specific kind of defect forms when part of the material’s crystal structure flips its orientation. Larger grains also make the alloys more flexible, allowing them to better adapt to surrounding biological tissues. This is the opposite of what happens with smaller grains, which facilitate inter-granular grain boundary sliding and make alloys more rigid.

The new work, which is detailed in Nature, could aid the development of advanced biodegradable implants for orthopaedics, cardiovascular applications and other devices, says Nei. “With improved biocompatibility, these implants could be safer and do away with the need for removal surgeries, lowering patient risk and healthcare costs,” he tells Physics World. “What is more, new alloys and processing techniques could allow for more personalized treatments by tailoring materials to specific medical needs, ultimately improving patient outcomes.”

The Monash team now aims to improve the composition of the alloys and achieve more control over how they degrade. “Further studies on animals and then clinical trials will test their strength, safety and compatibility with the body,” says Nei. “After that, regulatory approvals will ensure that the biodegradable metals meet medical standards for orthopaedic implants.”

The team is also setting up a start-up company with the goal of developing and commercializing the materials, he adds.

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How would the climate and the environment on our planet change if an asteroid struck? Researchers at the IBS Center for Climate Physics (ICCP) at Pusan National University in South Korea have now tried to answer this question by running several impact simulations with a state-of-the-art Earth system model on their in-house supercomputer. The results show that the climate, atmospheric chemistry and even global photosynthesis would be dramatically disrupted in the three to four years following the event, due to the huge amounts of dust produced by the impact.

Beyond immediate effects such as scorching heat, earthquakes and tsunamis, an asteroid impact would have long-lasting effects on the climate because of the large quantities of aerosols and gases ejected into the atmosphere. Indeed, previous studies on the Chicxulub 10-km asteroid impact, which happened around 66 million years ago, revealed that dust, soot and sulphur led to a global “impact winter” and was very likely responsible for the dinosaurs going extinct during the Cretaceous/Paleogene period.

“This winter is characterized by reduced sunlight, because of the dust filtering it out, cold temperatures and decreased precipitation at the surface,” says Axel Timmermann, director of the ICCP and leader of this new study. “Severe ozone depletion would occur in the stratosphere too because of strong warming caused by the dust particles absorbing solar radiation there.”

These unfavourable climate conditions would inhibit plant growth via a decline in photosynthesis both on land and in the sea and would thus affect food productivity, Timmermann adds.

Something surprising and potentially positive would also happen though, he says: plankton in the ocean would recover within just six months and its abundance could even increase afterwards. Indeed, diatoms (silicate-rich algae) would be more plentiful than before the collision. This might be because the dust created by the asteroid is rich in iron, which would trigger plankton growth as it sinks into the ocean. These phytoplankton “blooms” could help alleviate emerging food crises triggered by the reduction in terrestrial productivity, at least for several years after the impact, explains Timmermann.

The effect of a “Bennu”-sized asteroid impact

In this latest study, published in Science Advances, the researchers simulated the effect of a “Bennu”-sized asteroid impact. Bennu is a so-called medium-sized asteroid with a diameter of around 500 m. This type of asteroid is more likely to impact Earth than the “planet killer” larger asteroids, but has been studied far less.

There is an estimated 0.037% chance of such an asteroid colliding with Earth in September 2182. While this probability is small, such an impact would be very serious, says Timmermann, and would lead to climate conditions similar to those observed after some of the largest volcanic eruptions in the last 100 000 years. “It is therefore important to assess the risk, which is the product of the probability and the damage that would be caused, rather than just the probability by itself,” he tells Physics World. “Our results can serve as useful benchmarks to estimate the range of environmental effects from future medium-sized asteroid collisions.”

The team ran the simulations on the IBS’ supercomputer Aleph using the Community Earth System Model Version 2 (CESM2) and the Whole Atmosphere Community Climate Model Version 6 (WACCM6). The simulations injected up to 400 million tonnes of dust into the stratosphere.

The climate effects of impact-dust aerosols mainly depend on their abundance in the atmosphere and how they evolve there. The simulations revealed that global mean temperatures would drop by 4° C, a value that’s comparable with the cooling estimated as a result of the Toba volcano erupting around 74 000 years ago (which emitted 2000 Tg (2×10¹⁵ g) of sulphur dioxide). Precipitation also decreased 15% worldwide and ozone dropped by a dramatic 32% in the first year following the asteroid impact.

Asteroid impacts may have shaped early human evolution

“On average, medium-sized asteroids collide with Earth about every 100 000 to 200 000 years,” says Timmermann. “This means that our early human ancestors may have experienced some of these medium-sized events. These may have impacted human evolution and even affected our species’ genetic makeup.”

The researchers admit that their model has some inherent limitations. For one, CESM2/WACCM6, like other modern climate models, is not designed and optimized to simulate the effects of massive amounts of aerosol injected into the atmosphere. Second, the researchers only focused on the asteroid colliding with the Earth’s land surface. This is obviously less likely than an impact on the ocean, because roughly 70% of Earth’s surface is covered by water, they say. “An impact in the ocean would inject large amounts of water vapour rather than climate-active aerosols such as dust, soot and sulphur into the atmosphere and this vapour needs to be better modelled – for example, for the effect it has on ozone loss,” they say.

The effect of the impact on specific regions on the planet also needs to be better simulated, the researchers add. Whether the asteroid impacts during winter or summer also needs to be accounted for since this can affect the extent of the climate changes that would occur.

Finally, as well as the dust nanoparticles investigated in this study, future work should also look at soot emissions from wildfires ignited by “impact “spherules”, and sulphur and CO₂ released from target evaporites, say Timmermann and colleagues. “The ‘impact winter’ would be intensified and prolonged if other aerosols such as soot and sulphur were taken into account.”

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A research team headed up at Linköping University in Sweden and Cornell University in the US has succeeded in recycling almost all of the components of perovskite solar cells using simple, non-toxic, water-based solvents. What’s more, the researchers were able to use the recycled components to make new perovskite solar cells with almost the same power conversion efficiency as those created from new materials. This work could pave the way to a sustainable perovskite solar economy, they say.

While solar energy is considered an environmentally friendly source of energy, most of the solar panels available today are based on silicon, which is difficult to recycle. This has led to the first generation of silicon solar panels, which are reaching the end of their life cycles, ending up in landfills, says Xun Xiao, one of the team members at Linköping University.

When developing emerging solar cell technologies, we therefore need to take recycling into consideration, adds one of the leaders of the new study, Feng Gao, also at Linköping. “If we don’t know how to recycle them, maybe we shouldn’t put them on the market at all.”

To this end, many countries around the world are imposing legal requirements on photovoltaic manufacturers, to ensure that they collect and recycle any solar cell waste they produce. These initiatives include the WEEE directive 2012/19/EU in the European Union and equivalent legislation in Asia and the US.

Perovskites are one of the most promising materials for making next-generation solar cells. Not only are they relatively inexpensive, they are also easy to fabricate, lightweight, flexible and transparent. This allows them to be placed on top of a variety of surfaces, unlike their silicon counterparts. And since they boast a power conversion efficiency (PCE) of more than 25%, this makes them comparable to existing photovoltaics on the market.

A shorter lifespan

One of their downsides, however, is that perovskite solar cells have a shorter lifespan than silicon solar cells. This means that recycling is even more critical for these materials. Today, perovskite solar cells are disassembled using dangerous solvents such as dimethylformamide, but Gao and colleagues have now developed a technique in which water can be used as the solvent.

Perovskites are crystalline materials with an ABX₃ structure, where A is caesium, methylammonium (MA) or formamidinium (FA); B is lead or tin; and X is chlorine, bromine or iodine. Solar cells made of these materials are composed of different layers: the hole/electron transport layers; the perovskite layer; indium tin oxide substrates; and cover glasses.

In their work, which they detail in Nature, the researchers succeeded in delaminating end-of-life devices layer by layer, using water containing three low-cost additives: sodium acetate, sodium iodide and hypophosphorous acid. Despite being able to dissolve organic iodide salts such as methylammonium iodide and formamidinium iodide, water only marginally dissolves lead iodide (about 0.044 g per 100 ml at 20 °C). The researchers therefore developed a way to increase the amount of lead iodide that dissolves in water by introducing acetate ions into the mix. These ions readily coordinate with lead ions, forming highly soluble lead acetate (about 44.31 g per 100 ml at 20 °C).

Once the degraded perovskites had dissolved in the aqueous solution, the researchers set about recovering pure and high-quality perovskite crystals from the solution. They did this by providing extra iodide ions to coordinate with lead. This resulted in [PbI]⁺ transitioning to [PbI₂]⁰ and eventually to [PbI₃]⁻ and the formation of the perovskite framework.

To remove the indium tin oxide substrates, the researchers sonicated these layers in a solution of water/ethanol (50%/50% volume ratio) for 15 min. Finally, they delaminated the cover glasses by placing the degraded solar cells on a hotplate preheated to 150 °C for 3 min.

They were able to apply their technology to recycle both MAPbI₃ and FAPbI₃ perovskites.

New devices made from the recycled perovskites had an average power conversion efficiency of 21.9 ± 1.1%, with the best samples clocking in at 23.4%. This represents an efficiency recovery of more than 99% compared with those prepared using fresh materials (which have a PCE of 22.1 ± 0.9%).

Looking forward, Gao and colleagues say they would now like to demonstrate that their technique works on a larger scale. “Our life-cycle assessment and techno-economic analysis has already confirmed that our strategy not only preserves raw materials, but also appreciably lowers overall manufacturing costs of solar cells made from perovskites,” says co-team leader Fengqi You, who works at Cornell University. “In particular, reclaiming the valuable layers in these devices drives down expenses and helps reduce the ‘levelized cost’ of electricity they produce, making the technology potentially more competitive and sustainable at scale,” he tells Physics World.

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