Bismuth has puzzled scientists for nearly 20 years. Notably, the question of whether it is topological – that is, whether electrons behave differently on its surface than they do inside it – gets different answers depending on whether you ask a theorist or an experimentalist. Researchers in Japan now say they have found a way to resolve this conflict. A mechanism called surface relaxation, they report, may have masked or “blocked” bismuth’s true topological nature.

The classic way of describing topology is to compare objects that have a hole, such as a doughnut or a coffee mug, with objects that don’t, such as a muffin. Although we usually think of doughnuts as having more in common with muffins than with mugs – you can’t eat a mug – the fact that they have the same number of holes means the mug and doughnut share topological features that the muffin does not.

While no-one has ever wondered whether they can eat an electron, scientists have long been curious about whether materials conduct electricity. As it turns out, topology is one way of answering that question.

“Previously, people classified materials as metallic or insulating,” says Yuki Fuseya, a quantum solid state physicist at Kobe University. Beginning in the 2000s, however, Fuseya says scientists started focusing more on the topology of the electrons’ complex wavefunctions. This enriched our understanding of how materials behave, because wavefunctions with apparently different shapes can share important topological features.

For example, if the topology of certain wavefunctions on a material’s surface corresponds to that of apparently different wavefunctions within its bulk, the material may be insulating in its bulk, yet still able to conduct electricity on its surface. Materials with this property are known as topological insulators, and they have garnered a huge amount of interest due to the possibility of exploiting them in quantum computing, spintronics and magnetic devices.

Topological or not topological

While it’s not possible to measure the topology of wavefunctions directly, it is generally possible to detect whether a material supports certain surface states. This information can then be used to infer something about its bulk using the so-called bulk-edge state correspondence.

In bismuth, the existence of these surface states ought to indicate that the bulk material is topologically trivial. However, experiments have delivered conflicting information.

Fuseya was intrigued. “If you look at the history of solid-state physics, many physical phenomena were found firstly in bismuth,” he tells Physics World. Examples include diamagnetism, the Seebeck effect and the Shubnikov-de Haas effect, as well as phenomena related to the giant spin Hall effect and the potential for Turing patterns that Fuseya discovered himself. “That’s one of the reasons why I am so interested in bismuth,” he says.

Fuseya’s interest attracted colleagues with different specialisms. Using density functional theory, Rikako Yaguchi of the University of Electro-Communications in Tokyo calculated that layers of bismuth’s crystal lattice expand, or relax, by 3-6% towards the surface. According to Fuseya, this might not have seemed noteworthy. However, since the team was already looking at bismuth’s topological properties, another colleague, Kazuki Koie, went ahead and calculated how this lattice expansion changed the material’s surface wavefunction.

These calculations showed that the expansion is, in fact, significant. This is because bismuth is close to the topological transition point, where a change in parameters can flip the shape of the wavefunction and give topological properties to a material that was once topologically trivial. Consequently, the reason it is not possible to observe surface states indicating that bulk bismuth is topologically trivial is that the material is effectively different – and topologically non-trivial – on its surface.

Topological blocking

Although “very surprised” at first, Fuseya says that after examining the physics in more detail, they found the result “quite reasonable”. They are now looking for evidence of similar “topological blocking” in other materials near the transition point, such as lead telluride and tin telluride.

“It is remarkable that there are still big puzzles when trying to match data to the theoretical predictions,” says Titus Mangham Neupert, a theoretical physicist at the University of Zurich, Switzerland, who was not directly involved in the research. Since “so many compounds that made the headlines in topological physics” contain bismuth, Neupert says it will be interesting to re-evaluate existing experiments and conceive new ones. “In particular, the implication for higher-order topology could be tested,” he says.

Fuseya’s team is already studying how lattice relaxation might affect hinges where two surfaces come together. In doing so, they hope to understand why angle resolved photoemission spectroscopy (ARPES), which probes surfaces, yields results that contradict those from scanning tunnelling microscopy experiments, which probe hinges. “Maybe we can find a way to explain every experiment consistently,” Fuseya says. The insights they gain, he adds, might also be useful for topological engineering: by bending a material, scientists could alter its lattice constants, and thereby tailor its topological properties.

This aspect also interests Zeila Zanolli and Matthieu Verstraete of Utrecht University in the Netherlands. Though not involved in the current study, they had previously shown that free-standing two-dimensional bismuth (bismuthene) can take on several geometric structures in-plane – not all of which are topological – depending on the material’s strain, bonding coordination and directionality. The new work, they say, “opens the way to (computational) design of topological materials, playing with symmetries, strain and the substrate interface”.

The research is published in Physical Review B.

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Physicists have observed axion quasiparticles for the first time in a two-dimensional quantum material. As well as having applications in materials science, the discovery could aid the search for fundamental axions, which are a promising (but so far hypothetical) candidate for the unseen dark matter pervading our universe.

Theorists first proposed axions in the 1970s as a way of solving a puzzle involving the strong nuclear force and charge-parity (CP) symmetry. In systems that obey this symmetry, the laws of physics are the same for a particle and the spatial mirror image of its oppositely charged antiparticle. Weak interactions are known to violate CP symmetry, and the theory of quantum chromodynamics (QCD) allows strong interactions to do so, too. However, no-one has ever seen evidence of this happening, and the so-called “strong CP problem” remains unresolved.

More recently, the axion has attracted attention as a potential constituent of dark matter – the mysterious substance that appears to make up more than 85% of matter in the universe. Axions are an attractive dark matter candidate because while they do have mass, and theory predicts that the Big Bang should have generated them in large numbers, they are much less massive than electrons, and they carry no charge. This combination means that axions interact only very weakly with matter and electromagnetic radiation – exactly the behaviour we expect to see from dark matter.

Despite many searches, though, axions have never been detected directly. Now, however, a team of physicists led by Jianxiang Qiu of Harvard University has proposed a new detection strategy based on quasiparticles that are axions’ condensed-matter analogue. According to Qiu and colleagues, these quasiparticle axions, as they are known, could serve as axion “simulators”, and might offer a route to detecting dark matter in quantum materials.

Topological antiferromagnet

To detect axion quasiparticles, the Harvard team constructed gated electronic devices made from several two-dimensional layers of manganese bismuth telluride (MnBi₂Te₄). This material is a rare example of a topological antiferromagnet – that is, a material that is insulating in its bulk while conducting electricity on its surface, and that has magnetic moments that point in opposite directions. These properties allow quasiparticles known as magnons (collective oscillations of spin magnetic moments) to appear in and travel through the MnBi₂Te₄. Two types of magnon mode are possible: one in which the spins oscillate in sync; and another in which they are out of phase.

Qiu and colleagues applied a static magnetic field across the plane of their MnBi₂Te₄ sheets and bombarded the devices with sub-picosecond light pulses from a laser. This technique, known as ultrafast pump-probe spectroscopy, allowed them to observe the 44 GHz coherent oscillation of the so-called condensed-matter field. This field is the CP-violating term in QCD, and it is proportional to a material’s magnetoelectric coupling constant. “This is uniquely enabled by the out-of-phase magnon in this topological material,” explains Qiu. “Such coherent oscillations are the smoking-gun evidence for the axion quasiparticle and it is the combination of topology and magnetism in MnBi₂Te₄ that gives rise to it.”

A laboratory for axion studies

Now that they have detected axion quasiparticles, Qiu and colleagues say their next step will be to do experiments that involve hybridizing them with particles such as photons. Such experiments would create a new type of “axion-polariton” that would couple to a magnetic field in a unique way – something that could be useful for applications in ultrafast antiferromagnetic spintronics, in which spin-polarized currents can be controlled with an electric field.

The axion quasiparticle could also be used to build an axion dark matter detector. According to the team’s estimates, the detection frequency for the quasiparticle is in the milli-electronvolt (meV) range. While several theories for the axion predict that it could have a mass in this range, most existing laboratory detectors and astrophysical observations search for masses outside this window.

“The main technical barrier to building such a detector would be grow high-quality large crystals of MnBi₂Te₄ to maximize sensitivity,” Qiu tells Physics World. “In contrast to other high-energy experiments, such a detector would not require expensive accelerators or giant magnets, but it will require extensive materials engineering.”

The research is described in Nature.

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