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Anyon physics could explain coexistence of superconductivity and magnetism

New calculations by physicists in the US provide deeper insights into an exotic material in which superconductivity and magnetism can coexist. Using a specialized effective field theory, Zhengyan Shi and Todadri Senthil at the Massachusetts Institute of Technology show how this coexistence can emerge from the collective states of mobile anyons in certain 2D materials.

An anyon is a quasiparticle with statistical properties that lie somewhere between those of bosons and fermions. First observed in 2D electron gases in strong magnetic fields, anyons are known for their fractional electrical charge and fractional exchange statistics, which alter the quantum state of two identical anyons when they are exchanged for each other.

Unlike ordinary electrons, anyons produced in these early experiments could not move freely, preventing them from forming complex collective states. Yet in 2023, experiments with a twisted bilayer of molybdenum ditelluride provided the first evidence for mobile anyons through observations of fractional quantum anomalous Hall (FQAH) insulators. This effect appears as fractionally quantized electrical resistance in 2D electron systems at zero applied magnetic field.

Remarkably, these experiments revealed that molybdenum ditelluride can exhibit superconductivity and magnetism at the same time. Since superconductivity usually relies on electron pairing that can be disrupted by magnetism, this coexistence was previously thought impossible.

Anyonic quantum matter

“This then raises a new set of theoretical questions,” explains Shi. “What happens when a large number of mobile anyons are assembled together? What kind of novel ‘anyonic quantum matter’ can emerge?”

In their study, Shi and Senthil explored these questions using a new effective field theory for an FQAH insulator. Effective field theories are widely used in physics to approximate complex phenomena without modelling every microscopic detail. In this case, the duo’s model captured the competition between anyon mobility, interactions, and fractional exchange statistics in a many-body system of mobile anyons.

To test their model, the researchers considered the doping of an FQAH insulator – adding mobile anyons beyond the plateau in Hall resistance, where the existing anyons were effectively locked in place. This allowed the quasiparticles to move freely and form new collective phases.

“Crucially, we recognized that the fate of the doped state depends on the energetic hierarchy of different types of anyons,” Shi explains. “This observation allowed us to develop a powerful heuristic for predicting whether the doped state becomes a superconductor without any detailed calculations.”

In their model, Shi and Senthil focused on a specific FQAH insulator called a Jain state, which hosts two types of anyon excitations. One type has electrical charge of 1/3 of an electron and the other with 2/3. In a perfectly clean system, doping the insulator with 2/3-charge anyons produced a chiral topological superconductor, a phase that is robust against disorder and features edge currents flowing in only one direction. In contrast, doping with 1/3-charge anyons produced a metal with broken translation symmetry – still conducting, but with non-uniform patterns in its electron density.

Anomalous vortex glass

“In the presence of impurities, we showed that the chiral superconductor near the superconductor–insulator transition is a novel phase of matter dubbed the ‘anomalous vortex glass’, in which patches of swirling supercurrents are sprinkled randomly across the sample,” Shi describes. “Observing this vortex glass phase would be smoking-gun evidence for the anyonic mechanism for superconductivity.”

The results suggest that even when adding the simplest kind of anyons – like those in the Jain state – the collective behaviour of these quasiparticles can enable the coexistence of magnetism and superconductivity. In future studies, the duo hopes that more advanced methods for introducing mobile anyons could reveal even more exotic phases.

“Remarkably, our theory provides a qualitative account of the phase diagram of a particular 2D material (twisted molybdenum ditelluride), although many more tests are needed to rule out other possible explanations,” Shi says. “Overall, these findings highlight the vast potential of anyonic quantum matter, suggesting a fertile ground for future discoveries.”

The research is described in PNAS.

The post Anyon physics could explain coexistence of superconductivity and magnetism appeared first on Physics World.

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Slow spectroscopy sheds light on photodegradation

Using a novel spectroscopy technique, physicists in Japan have revealed how organic materials accumulate electrical charge through long-term illumination by sunlight – leading to material degradation. Ryota Kabe and colleagues at the Okinawa Institute of Science and Technology have shown how charge separation occurs gradually via a rare multi-photon ionization process, offering new insights into how plastics and organic semiconductors degrade in sunlight.

In a typical organic solar cell, an electron-donating material is interfaced with an electron acceptor. When the donor absorbs a photon, one of its electrons may jump across the interface, creating a bound electron-hole pair which may eventually dissociate – creating two free charges from which useful electrical work can be extracted.

Although such an interface vastly boosts the efficiency of this process, it is not necessary for charge separation to occur when an electron donor is illuminated. “Even single-component materials can generate tiny amounts of charge via multiphoton ionization,” Kabe explains. “However, experimental evidence has been scarce due to the extremely low probability of this process.”

To trigger charge separation in this way, an electron needs to absorb one or more additional photons while in its excited state. Since the vast majority of electrons fall back into their ground states before this can happen, the spectroscopic signature of this charge separation is very weak. This makes it incredibly difficult to detect using conventional spectroscopy techniques, which can generally only make observations over timescales of up to a few milliseconds.

The opposite approach

“While weak multiphoton pathways are easily buried under much stronger excited-state signals, we took the opposite approach in our work,” Kabe describes. “We excited samples for long durations and searched for traces of accumulated charges in the slow emission decay.”

Key to this approach was an electron donor called NPD. This organic material has a relatively long triplet lifetime, where an excited electron is prevented from transitioning back to its ground state. As a result, these molecules emit phosphorescence over relatively long timescales.

In addition, Kabe’s team dispersed their NPD samples into different host materials with carefully selected energy levels. In one medium, the energies of both the highest-occupied and lowest-unoccupied molecular orbitals lay below NPD’s corresponding levels, so that the host material acted as an electron acceptor. As a result, charge transfer occurred in the same way as it would across a typical donor-acceptor interface.

Yet in another medium, the host’s lowest-unoccupied orbital lay above NPD’s – blocking charge transfer, and allowing triplet states to accumulate instead. In this case, the only way for charge separation to occur was through multi-photon ionization.

Slow emission decay analysis

Since NPD’s long triplet lifetime allowed its electrons to be excited gradually over an extended period of illumination, its weak charge accumulation became detectable through slow emission decay analysis. In contrast, more conventional methods involve multiple, ultra-fast laser pulses, severely restricting the timescale over which measurements can be made. Altogether, this approach enabled the team to clearly distinguish between the two charge generation pathways.

“Using this method, we confirmed that charge generation occurred via resonance-enhanced multiphoton ionization mediated by long-lived triplet states, even in single-component organic materials,” Kabe describes.

This result offers insights into how plastics and organic semiconductors are degraded by sunlight over years or decades. The conventional explanation is that sunlight generates free radicals. These are molecules that lose an electron through ionization, leaving behind an unpaired electron which readily reacts with other molecules in the surrounding environment. Since photodegradation unfolds over such a long timescale, researchers could not observe this charge generation in single-component organic materials – until now.

“The method will be useful for analysing charge behaviour in organic semiconductor devices and for understanding long-term processes such as photodegradation that occur gradually under continuous light exposure,” Kabe says.

The research is described in Science Advances.

The post Slow spectroscopy sheds light on photodegradation appeared first on Physics World.

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