Helium deep with the Earth could bond with iron to form stable compounds – according to experiments done by scientists in Japan and Taiwan. The work was done by Haruki Takezawa and Kei Hirose at the University of Tokyo and colleagues, who suggest that Earth’s core could host a vast reservoir of primordial helium-3 – reshaping our understanding of the planet’s interior.

Noble gases including helium are normally chemically inert. But under extreme pressures, heavier members of the group (including xenon and krypton) can form a variety of compounds with other elements. To date, however, less is known about compounds containing helium – the lightest noble gas.

Beyond the synthesis of disodium helide (Na₂He) in 2016, and a handful of molecules in which helium forms weak van der Waals bonds with other atoms, the existence of other helium compounds has remained purely theoretical.

As a result, the conventional view is that any primordial helium-3 present when our planet first formed would have quickly diffused through Earth’s interior, before escaping into the atmosphere and then into space.

Tantalizing clues

However, there are tantalizing clues that helium compounds could exist in some volcanic rocks on Earth’s surface. These rocks contain unusually high isotopic ratios of helium-3 to helium-4. “Unlike helium-4, which is produced through radioactivity, helium-3 is primordial and not produced in planetary interiors,” explains Hirose. “Based on volcanic rock measurements, helium-3 is known to be enriched in hot magma, which originally derives from hot plumes coming from deep within Earth’s mantle.” The mantle is the region between Earth’s core and crust.

The fact that the isotope can still be found in rock and magma suggests that it must have somehow become trapped in the Earth. “This argument suggests that helium-3 was incorporated into the iron-rich core during Earth’s formation, some of which leaked from the core to the mantle,” Hirose explains.

It could be that the extreme pressures present in Earth’s iron-rich core enabled primordial helium-3 to bond with iron to form stable molecular lattices. To date, however, this possibility has never been explored experimentally.

Now, Takezawa, Hirose and colleagues have triggered reactions between iron and helium within a laser-heated diamond-anvil cell. Such cells crush small samples to extreme pressures – in this case as high as 54 GPa. While this is less than the pressure in the core (about 350 GPa), the reactions created molecular lattices of iron and helium. These structures remained stable even when the diamond-anvil’s extreme pressure was released.

To determine the molecular structures of the compounds, the researchers did X-ray diffraction experiments at Japan’s SPring-8 synchrotron. The team also used secondary ion mass spectrometry to determine the concentration of helium within their samples.

Synchrotron and mass spectrometer

“We also performed first-principles calculations to support experimental findings,” Hirose adds. “Our calculations also revealed a dynamically stable crystal structure, supporting our experimental findings.” Altogether, this combination of experiments and calculations showed that the reaction could form two distinct lattices (face-centred cubic and distorted hexagonal close packed), each with differing ratios of iron to helium atoms.

These results suggest that similar reactions between helium and iron may have occurred within Earth’s core shortly after its formation, trapping much of the primordial helium-3 in the material that coalesced to form Earth. This would have created a vast reservoir of helium in the core, which is gradually making its way to the surface.

However, further experiments are needed to confirm this thesis. “For the next step, we need to see the partitioning of helium between iron in the core and silicate in the mantle under high temperatures and pressures,” Hirose explains.

Observing this partitioning would help rule out the lingering possibility that unbonded helium-3 could be more abundant than expected within the mantle – where it could be trapped by some other mechanism. Either way, further studies would improve our understanding of Earth’s interior composition – and could even tell us more about the gases present when the solar system formed.

The research is described in Physical Review Letters.

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A new technique for using frequency combs to measure trace concentrations of gas molecules has been developed by researchers in the US. The team reports single-digit parts-per-trillion detection sensitivity, and extreme broadband coverage over 1000 cm^-1 wavenumbers. This record-level sensing performance could open up a variety of hitherto inaccessible applications in fields such as medicine, environmental chemistry and chemical kinetics.

Each molecular species will absorb light at a specific set of frequencies. So, shining light through a sample of gas and measuring this absorption can reveal the molecular composition of the gas.

Cavity ringdown spectroscopy is an established way to increase the sensitivity of absorption spectroscopy and needs no calibration. A laser is injected between two mirrors, creating an optical standing wave. A sample of gas is then injected into the cavity, so the laser beam passes through it, normally many thousands of times. The absorption of light by the gas is then determined by the rate at which the intracavity light intensity “rings down” – in other words, the rate at which the standing wave decays away.

Researchers have used this method with frequency comb lasers to probe the absorption of gas samples at a range of different light frequencies. A frequency comb produces light at a series of very sharp intensity peaks that are equidistant in frequency – resembling the teeth of a comb.

Shifting resonances

However, the more reflective the mirrors become (the higher the cavity finesse), the narrower each cavity resonance becomes. Due to the fact that their frequencies are not evenly spaced and can be heavily altered by the loaded gas, normally one relies on creating oscillations in the length of the cavity. This creates shifts in all the cavity resonance frequencies to modulate around the comb lines. Multiple resonances are sequentially excited and the transient comb intensity dynamics are captured by a camera, following spatial separation by an optical grating.

“That experimental scheme works in the near-infrared, but not in the mid-infrared,” says Qizhong Liang. “Mid-infrared cameras are not fast enough to capture those dynamics yet.” This is a problem because the mid-infrared is where many molecules can be identified by their unique absorption spectra.

Liang is a member of Jun Ye’s group in JILA in Colorado, which has shown that it is possible to measure transient comb dynamics simply with a Michelson interferometer. The spectrometer entails only beam splitters, a delay stage, and photodetectors. The researchers worked out that, the periodically generated intensity dynamics arising from each tooth of the frequency comb can be detected as a set of Fourier components offset by Doppler frequency shifts. Absorption from the loaded gas can thus be determined.

Dithering the cavity

This process of reading out transient dynamics from “dithering” the cavity by a passive Michelson interferometer is much simpler than previous setups and thus can be used by people with little experience with combs, says Liang. It also places no restrictions on the finesse of the cavity, spectral resolution, or spectral coverage. “If you’re dithering the cavity resonances, then no matter how narrow the cavity resonance is, it’s guaranteed that the comb lines can be deterministically coupled to the cavity resonance twice per cavity round trip modulation,” he explains.

The researchers reported detections of various molecules at concentrations as low as parts-per-billion with parts-per-trillion uncertainty in exhaled air from volunteers. This included biomedically relevant molecules such as acetone, which is a sign of diabetes, and formaldehyde, which is diagnostic of lung cancer. “Detection of molecules in exhaled breath in medicine has been done in the past,” explains Liang. “The more important point here is that, even if you have no prior knowledge about what the gas sample composition is, be it in industrial applications, environmental science applications or whatever you can still use it.”

Konstantin Vodopyanov of the University of Central Florida in Orlando comments: “This achievement is remarkable, as it integrates two cutting-edge techniques: cavity ringdown spectroscopy, where a high-finesse optical cavity dramatically extends the laser beam’s path to enhance sensitivity in detecting weak molecular resonances, and frequency combs, which serve as a precise frequency ruler composed of ultra-sharp spectral lines. By further refining the spectral resolution to the Doppler broadening limit of less than 100 MHz and referencing the absolute frequency scale to a reliable frequency standard, this technology holds great promise for applications such as trace gas detection and medical breath analysis.”

The spectrometer is described in Nature.

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Vacuum technology is routinely used in both scientific research and industrial processes. In physics, high-quality vacuum systems make it possible to study materials under extremely clean and stable conditions. In industry, vacuum is used to lift, position and move objects precisely and reliably. Without these technologies, a great deal of research and development would simply not happen. But for all its advantages, working under vacuum does come with certain challenges. For example, once something is inside a vacuum system, how do you manipulate it without opening the system up?

The UK-based firm UHV Design has been working on this problem for over a quarter of a century, developing and manufacturing vacuum manipulation solutions for new research disciplines as well as emerging industrial applications. Its products, which are based on magnetically coupled linear and rotary probes, are widely used at laboratories around the world, in areas ranging from nanoscience to synchrotron and beamline applications. According to engineering director Jonty Eyres, the firm’s latest innovation – a new sample transfer arm released at the beginning of this year – extends this well-established range into new territory.

“The new product is a magnetically coupled probe that allows you to move a sample from point A to point B in a vacuum system,” Eyres explains. “It was designed to have an order of magnitude improvement in terms of both linear and rotary motion thanks to the magnets in it being arranged in a particular way. It is thus able to move and position objects that are much heavier than was previously possible.”

The new sample arm, Eyres explains, is made up of a vacuum “envelope” comprising a welded flange and tube assembly. This assembly has an outer magnet array that magnetically couples to an inner magnet array attached to an output shaft. The output shaft extends beyond the mounting flange and incorporates a support bearing assembly. “Depending on the model, the shafts can either be in one or more axes: they move samples around either linearly, linear/rotary or incorporating a dual axis to actuate a gripper or equivalent elevating plate,” Eyres says.

Continual development, review and improvement

While similar devices are already on the market, Eyres says that the new product has a significantly larger magnetic coupling strength in terms of its linear thrust and rotary torque. These features were developed in close collaboration with customers who expressed a need for arms that could carry heavier payloads and move them with more precision. In particular, Eyres notes that in the original product, the maximum weight that could be placed on the end of the shaft – a parameter that depends on the stiffness of the shaft as well as the magnetic coupling strength – was too small for these customers’ applications.

“From our point of view, it was not so much the magnetic coupling that needed to be reviewed, but the stiffness of the device in terms of the size of the shaft that extends out to the vacuum system,” Eyres explains. “The new arm deflects much less from its original position even with a heavier load and when moving objects over longer distances.”

The new product – a scaled-up version of the original – can move an object with a mass of up to 50 N (5 kg) over an axial stroke of up to 1.5 m. Eyres notes that it also requires minimal maintenance, which is important for moving higher loads. “It is thus targeted to customers who wish to move larger objects around over longer periods of time without having to worry about intervening too often,” he says.

Moving multiple objects

As well as moving larger, single objects, the new arm’s capabilities make it suitable for moving multiple objects at once. “Rather than having one sample go through at a time, we might want to nest three or four samples onto a large plate, which inevitably increases the size of the overall object,” Eyres explains.

Before they created this product, he continues, he and his UHV Design colleagues were not aware of any magnetic coupled solution on the marketplace that enabled users to do this. “As well as being capable of moving heavy samples, our product can also move lighter samples, but with a lot less shaft deflection over the stroke of the product,” he says. “This could be important for researchers, particularly if they are limited in space or if they wish to avoid adding costly supports in their vacuum system.”

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